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The use of glass particles and its consequences in late 16th century oil painting: A Portuguese case based on the analytical results and the technical treatises

dc.contributor.authorMelo, Helena P.
dc.contributor.authorCruz, António João
dc.contributor.authorValadas, Sara
dc.contributor.authorCardoso, Ana Margarida
dc.contributor.authorCandeias, António
dc.date.accessioned2024-01-15T16:59:12Z
dc.date.available2024-01-15T16:59:12Z
dc.date.issued2020
dc.date.updated2024-01-15T16:17:07Z
dc.description.abstractColourless glass particles were identified for the first time in Portuguese paintings in two altarpieces attributed to the painter Francisco João, active between 1558 and 1595. They were found in red glazes with conservation problems. The glass was analysed by SEM-EDX and the binder by μ-FTIR. Portuguese 17th century painting treatises, which record earlier practices, were examined providing additional information. The glass particles had a vegetable silica-soda-lime composition, different in the two altarpieces, and a medium to very high alumina content. Although the provenance of the glass could not be determined, the use of local glass is suggested, as archaeological glass of the same period and similar composition has been found in southern Europe, notably Portugal. Furthermore, the glass from one of the altarpieces closely matches the composition of glass found in a painting by the Spaniard Luis de Morales. As a result, it is possible that the painter deliberately added a local glass to his red lakes, as advised in the two Portuguese painting treatises of this period. The exclusive presence of glass in the uppermost medium-rich glazes suggests that it was mainly used for its transparency and assumed siccative role. Although the siccative properties of glass have not been proved, by lowering the oil concentration in the paint, the addition of glass might have indirectly assisted the drying of the glazes. The glass particles were subject to a severe leaching of the alkali, a degradation that might explain the disruption of the glaze layers in these paintings.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.doi10.1016/j.culher.2019.11.001pt_PT
dc.identifier.eid2-s2.0-85076510970
dc.identifier.issn1296-2074
dc.identifier.slugcv-prod-911109
dc.identifier.urihttp://hdl.handle.net/10400.26/48956
dc.language.isoengpt_PT
dc.relation.publisherversionhttps://www.sciencedirect.com/science/article/abs/pii/S1296207419301049pt_PT
dc.subjectRed lakept_PT
dc.subjectGround glasspt_PT
dc.subjectOil paintingpt_PT
dc.subjectPainting techniquept_PT
dc.subjectPainting treatisespt_PT
dc.subjectDeteriorationpt_PT
dc.titleThe use of glass particles and its consequences in late 16th century oil painting: A Portuguese case based on the analytical results and the technical treatisespt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.citation.endPage270pt_PT
oaire.citation.startPage261pt_PT
oaire.citation.titleJournal of Cultural Heritagept_PT
oaire.citation.volume43pt_PT
person.familyNameCruz
person.givenNameAntónio João
person.identifier.ciencia-id411C-A14B-142F
person.identifier.orcid0000-0001-6396-5027
person.identifier.ridA-3763-2008
person.identifier.scopus-author-id10039472900
rcaap.cv.cienciaid411C-A14B-142F | António João Cruz
rcaap.rightsclosedAccesspt_PT
rcaap.typearticlept_PT
relation.isAuthorOfPublication64a39025-219e-48bb-98a0-46f5f8d94881
relation.isAuthorOfPublication.latestForDiscovery64a39025-219e-48bb-98a0-46f5f8d94881

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