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Modelling higher heating value of different separated fractions from municipal and construction and demolition wastes

dc.contributor.authorAlves, Octávio
dc.contributor.authorGonçalves, Margarida
dc.contributor.authorBrito, Paulo
dc.contributor.authorMonteiro, Eliseu
dc.date.accessioned2018-12-05T12:27:40Z
dc.date.available2018-12-05T12:27:40Z
dc.date.issued2018
dc.description.abstractHigher heating value (HHV) is an important property of biomass and wastes used to evaluate their potential conversion to useful thermal or electric energy. Because the measurement of this property requires expensive resources and is somewhat time-consuming, many works focused their attention on the determination of mathematic models relating the HHV with the composition of lignocellulosic biomass or other fuel materials, such as their ultimate and proximate analysis. These models can supply appropriate estimates of HHV but only for analogous materials, so they should not be used to compare samples with marked differences in composition or physical and chemical properties. In this work, 9 different separated fractions of municipal and construction and demolition wastes (wood, paper/card, plastics, sewage sludge and mixtures among them) were used to deduce a mathematical expression relating HHV with their contents of carbon, hydrogen, oxygen, nitrogen, sulphur and ash. For this purpose, HHV's, proximate and ultimate analysis were experimentally obtained and the results used to create three different expressions applying linear regression methods. The best expression was selected and validated by comparing deviations among the calculated results and those retrieved from the literature and from experimental measurements regarding different wastes. It was concluded that the best expression was HHV (MJ/kg db) = 0.3845×C+0.8831×H- 29.1217×S-0.0630×O-1.0063×N+0.3888×ASH-0.2546 (with C, H, S, O, N and ASH in wt% db, considering atomic ratios O/C and H/C within 0.0O/C1.2 and 0.1H/C0.2), giving an average absolute error of 8.5 % and an average bias error of -1.6 %. However, appreciable deviations may be found when estimating the HHV of polyurethane, paper/card, mixtures of paper/plastic and sewage sludge and thus the application of the expression for these materials is questionable.pt_PT
dc.description.sponsorshipPOCI-01-0145-FEDER-024020
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.urihttp://hdl.handle.net/10400.26/25187
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.relationAproveitamento Energético de Combustíveis Derivados de Resíduos via Co-Gaseificação Térmica
dc.subjectHigher Heating Valuept_PT
dc.subjectModellingpt_PT
dc.subjectMunicipal Wastept_PT
dc.subjectConstruction and Demolition Wastept_PT
dc.titleModelling higher heating value of different separated fractions from municipal and construction and demolition wastespt_PT
dc.typeconference object
dspace.entity.typePublication
oaire.awardTitleAproveitamento Energético de Combustíveis Derivados de Resíduos via Co-Gaseificação Térmica
oaire.awardURIinfo:eu-repo/grantAgreement/FCT//SFRH%2FBD%2F111956%2F2015/PT
oaire.citation.conferencePlaceGuimarãespt_PT
oaire.citation.titlePROCEEDINGS OF ECOS 2018 - THE 31ST INTERNATIONAL CONFERENCE ON EFFICIENCY, COST, OPTIMIZATION, SIMULATION AND ENVIRONMENTAL IMPACT OF ENERGY SYSTEMSpt_PT
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsopenAccesspt_PT
rcaap.typeconferenceObjectpt_PT
relation.isProjectOfPublicationbe003ea4-daf6-402b-b71a-a8ae13f5b7f2
relation.isProjectOfPublication.latestForDiscoverybe003ea4-daf6-402b-b71a-a8ae13f5b7f2

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