Logo do repositório
 
Publicação

Molybdenum(II) Diiodo-Tricarbonyl Complexes Containing Nitrogen Donor Ligands as Catalyst Precursors for the Epoxidation of Methyl Oleate

2012Artigo científico Acesso restrito
Ver registo simples
dc.contributor.authorGamelas ou Carla A. Gamelas, Carla
dc.contributor.authorNeves, P.
dc.contributor.authorGomes, A. C.
dc.contributor.authorValente, A.
dc.contributor.authorRomão, C.
dc.contributor.authorGonçalves, I.
dc.contributor.authorPillinger, M.
dc.date.accessioned2018-03-22T14:56:21Z
dc.date.available2018-03-22T14:56:21Z
dc.date.issued2012
dc.description.abstractThe molybdenum(II) tricarbonyl complexes [Mo(CO)3I2L n ] (n = 1, L = 2,2′-bipyridine, 4,4′-di-tert-butyl-2,2′-bipyridine; n = 2, L = pyridine, 4-tert-butylpyridine) have been examined as catalyst precursors for the epoxidation of the biorenewable olefin methyl oleate with tert-butylhydroperoxide. In situ oxidative decarbonylation of the precursors gives highly active and selective molybdenum(VI) catalysts, which were identified as the one-dimensional molybdenum oxide/bipyridine polymer [MoO3(2,2′-bipyridine)], octanuclear [Mo8O24(4,4′-di-tert-butyl-2,2′-bipyridine)4], and the pyridinium β-octamolybdates (LH)4[Mo8O26] for L = pyridine or 4-tert-butylpyridine.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationGamelas, C., Neves, P., Gomes, A., Valente, A., Romão C., Gonçalves, I. & Pillinger, M.(2012). Molybdenum(II) Diiodo-Tricarbonyl Complexes Containing Nitrogen Donor Ligands as Catalyst Precursors for the Epoxidation of Methyl Oleate. Catalysis Letters, 142, pp. 1218-1224.pt_PT
dc.identifier.doi10.1007/s10562-012-0890-5
dc.identifier.urihttp://hdl.handle.net/10400.26/22036
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.titleMolybdenum(II) Diiodo-Tricarbonyl Complexes Containing Nitrogen Donor Ligands as Catalyst Precursors for the Epoxidation of Methyl Oleatept_PT
dc.typejournal article
dspace.entity.typePublication
oaire.citation.titleCatalysis Letterspt_PT
person.familyNameGamelas Albuquerque Pinto Reis
person.givenNameCarla Alexandra
person.identifier.ciencia-id2219-54F2-BB9D
rcaap.rightsclosedAccesspt_PT
rcaap.typearticlept_PT
relation.isAuthorOfPublicationa02aa459-55c4-4506-b8f2-5189e5c13124
relation.isAuthorOfPublication.latestForDiscoverya02aa459-55c4-4506-b8f2-5189e5c13124

Ficheiros

Principais
A mostrar 1 - 1 de 1
Miniatura indisponível
Nome:
Artigo 7-Catal. Lett. (2012) 142, 1218-1224.pdf
Tamanho:
288.88 KB
Formato:
Adobe Portable Document Format
Ver/Abrir
Licença
A mostrar 1 - 1 de 1
Miniatura indisponível
Nome:
license.txt
Tamanho:
1.85 KB
Formato:
Item-specific license agreed upon to submission
Descrição:
Ver/Abrir

Coleções

IPS - ESTS – DSI - Artigos científicos