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Molybdenum(II) Diiodo-Tricarbonyl Complexes Containing Nitrogen Donor Ligands as Catalyst Precursors for the Epoxidation of Methyl Oleate

2012Journal article Restricted access
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dc.contributor.authorGamelas ou Carla A. Gamelas, Carla
dc.contributor.authorNeves, P.
dc.contributor.authorGomes, A. C.
dc.contributor.authorValente, A.
dc.contributor.authorRomão, C.
dc.contributor.authorGonçalves, I.
dc.contributor.authorPillinger, M.
dc.date.accessioned2018-03-22T14:56:21Z
dc.date.available2018-03-22T14:56:21Z
dc.date.issued2012
dc.description.abstractThe molybdenum(II) tricarbonyl complexes [Mo(CO)3I2L n ] (n = 1, L = 2,2′-bipyridine, 4,4′-di-tert-butyl-2,2′-bipyridine; n = 2, L = pyridine, 4-tert-butylpyridine) have been examined as catalyst precursors for the epoxidation of the biorenewable olefin methyl oleate with tert-butylhydroperoxide. In situ oxidative decarbonylation of the precursors gives highly active and selective molybdenum(VI) catalysts, which were identified as the one-dimensional molybdenum oxide/bipyridine polymer [MoO3(2,2′-bipyridine)], octanuclear [Mo8O24(4,4′-di-tert-butyl-2,2′-bipyridine)4], and the pyridinium β-octamolybdates (LH)4[Mo8O26] for L = pyridine or 4-tert-butylpyridine.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationGamelas, C., Neves, P., Gomes, A., Valente, A., Romão C., Gonçalves, I. & Pillinger, M.(2012). Molybdenum(II) Diiodo-Tricarbonyl Complexes Containing Nitrogen Donor Ligands as Catalyst Precursors for the Epoxidation of Methyl Oleate. Catalysis Letters, 142, pp. 1218-1224.pt_PT
dc.identifier.doi10.1007/s10562-012-0890-5
dc.identifier.urihttp://hdl.handle.net/10400.26/22036
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.titleMolybdenum(II) Diiodo-Tricarbonyl Complexes Containing Nitrogen Donor Ligands as Catalyst Precursors for the Epoxidation of Methyl Oleatept_PT
dc.typejournal article
dspace.entity.typePublication
oaire.citation.titleCatalysis Letterspt_PT
person.familyNameGamelas Albuquerque Pinto Reis
person.givenNameCarla Alexandra
person.identifier.ciencia-id2219-54F2-BB9D
rcaap.rightsclosedAccesspt_PT
rcaap.typearticlept_PT
relation.isAuthorOfPublicationa02aa459-55c4-4506-b8f2-5189e5c13124
relation.isAuthorOfPublication.latestForDiscoverya02aa459-55c4-4506-b8f2-5189e5c13124

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