Catalytic decomposition of potassium monopersulfate: the kinetics

Borralho, Maria Teresa; Gimeno, Olga; Rivas, Javier; Carbajo, Maria

http://hdl.handle.net/10400.26/1334

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Authors

Borralho, Maria Teresa

Gimeno, Olga

Rivas, Javier

Carbajo, Maria

Abstract(s)

Potassium monopersulfate has been decomposed in aqueous solution in the presence of Co(II). The process has been simulated by means of a mechanism based on elementary reactions. Rate constants have been taken from literature reports or, alternatively, assimilated to analogous reactions occurring in Fenton´s chemistry. Several operating conditions have been successfully applied.