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Oxido-bis¬[chlorido(4,4'-di-tert-butyl-2,2'-bipyridine-2N,N')dioxido¬molybdenum(VI)] 0.2-hydrate
| dc.contributor.author | Gomes, A. C. | |
| dc.contributor.author | Fernandes, J. A. | |
| dc.contributor.author | Gamelas ou Carla A. Gamelas, Carla | |
| dc.contributor.author | Gonçalves, I. S. | |
| dc.contributor.author | Almeida-Paz, F. A. | |
| dc.date.accessioned | 2018-03-13T14:54:57Z | |
| dc.date.available | 2018-03-13T14:54:57Z | |
| dc.date.issued | 2011 | |
| dc.description.abstract | The title hydrate, [Mo2Cl2O5(C18H24N2)2]·0.2H2O, has been isolated as the oxidation product of [Mo(3-C3H5)Cl(CO)2(di-t-Bu-bipy)] (where di-t-Bu-bipy is 4,4'-di-tert-butyl-2,2'-bipyridine). A -oxide ligand bridges two similar MoCl(di-t-Bu-bipy)O2 units, having the terminal oxide ligands mutually cis, and the chloride and -oxide trans to each other. In the binuclear complex, the coordination geometries of the metal atoms can be described as highly distorted octahedra. Individual complexes co-crystallize with a partially occupied water molecule of crystallization (occupancy factor = 0.20; H atoms not located), with the crystal packing being mediated by the need to effectively fill the available space. A number of weak C-HO and C-HCl interactions are present. | pt_PT |
| dc.description.version | info:eu-repo/semantics/publishedVersion | pt_PT |
| dc.identifier.citation | Gomes, A., Fernandes, J., Gamelas, C., Gonçalves, I. & Almeida-Paz, F. (2011). Oxido-bis¬[chlorido(4,4'-di-tert-butyl-2,2'-bipyridine-2N,N')dioxido¬molybdenum(VI)] 0.2-hydrate. Acta Crystallographica Section E: Structure Reports Online, 67 (12), m1738-m1739. doi: 10.1107/S1600536811046952 | pt_PT |
| dc.identifier.doi | 10.1107/S1600536811046952 | pt_PT |
| dc.identifier.uri | http://hdl.handle.net/10400.26/21982 | |
| dc.language.iso | eng | pt_PT |
| dc.peerreviewed | yes | pt_PT |
| dc.title | Oxido-bis¬[chlorido(4,4'-di-tert-butyl-2,2'-bipyridine-2N,N')dioxido¬molybdenum(VI)] 0.2-hydrate | pt_PT |
| dc.type | journal article | |
| dspace.entity.type | Publication | |
| oaire.citation.title | Acta Crystallographica Section E: Structure Reports Online | pt_PT |
| person.familyName | Gamelas Albuquerque Pinto Reis | |
| person.givenName | Carla Alexandra | |
| person.identifier.ciencia-id | 2219-54F2-BB9D | |
| rcaap.rights | openAccess | pt_PT |
| rcaap.type | article | pt_PT |
| relation.isAuthorOfPublication | a02aa459-55c4-4506-b8f2-5189e5c13124 | |
| relation.isAuthorOfPublication.latestForDiscovery | a02aa459-55c4-4506-b8f2-5189e5c13124 |
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