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Oxido-bis¬[chlorido(4,4'-di-tert-butyl-2,2'-bipyridine-2N,N')dioxido¬molybdenum(VI)] 0.2-hydrate

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dc.contributor.authorGomes, A. C.
dc.contributor.authorFernandes, J. A.
dc.contributor.authorGamelas ou Carla A. Gamelas, Carla
dc.contributor.authorGonçalves, I. S.
dc.contributor.authorAlmeida-Paz, F. A.
dc.date.accessioned2018-03-13T14:54:57Z
dc.date.available2018-03-13T14:54:57Z
dc.date.issued2011
dc.description.abstractThe title hydrate, [Mo2Cl2O5(C18H24N2)2]·0.2H2O, has been isolated as the oxidation product of [Mo(3-C3H5)Cl(CO)2(di-t-Bu-bipy)] (where di-t-Bu-bipy is 4,4'-di-tert-butyl-2,2'-bipyridine). A -oxide ligand bridges two similar MoCl(di-t-Bu-bipy)O2 units, having the terminal oxide ligands mutually cis, and the chloride and -oxide trans to each other. In the binuclear complex, the coordination geometries of the metal atoms can be described as highly distorted octahedra. Individual complexes co-crystallize with a partially occupied water molecule of crystallization (occupancy factor = 0.20; H atoms not located), with the crystal packing being mediated by the need to effectively fill the available space. A number of weak C-HO and C-HCl interactions are present.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationGomes, A., Fernandes, J., Gamelas, C., Gonçalves, I. & Almeida-Paz, F. (2011). Oxido-bis¬[chlorido(4,4'-di-tert-butyl-2,2'-bipyridine-2N,N')dioxido¬molybdenum(VI)] 0.2-hydrate. Acta Crystallographica Section E: Structure Reports Online, 67 (12), m1738-m1739. doi: 10.1107/S1600536811046952pt_PT
dc.identifier.doi10.1107/S1600536811046952pt_PT
dc.identifier.urihttp://hdl.handle.net/10400.26/21982
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.titleOxido-bis¬[chlorido(4,4'-di-tert-butyl-2,2'-bipyridine-2N,N')dioxido¬molybdenum(VI)] 0.2-hydratept_PT
dc.typejournal article
dspace.entity.typePublication
oaire.citation.titleActa Crystallographica Section E: Structure Reports Onlinept_PT
person.familyNameGamelas Albuquerque Pinto Reis
person.givenNameCarla Alexandra
person.identifier.ciencia-id2219-54F2-BB9D
rcaap.rightsopenAccesspt_PT
rcaap.typearticlept_PT
relation.isAuthorOfPublicationa02aa459-55c4-4506-b8f2-5189e5c13124
relation.isAuthorOfPublication.latestForDiscoverya02aa459-55c4-4506-b8f2-5189e5c13124

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